Studies on Seven-membered Ring Compounds. XI. Bromination of 5-Hydroxycyclohepta [b] pyrrol-6 (1H)-one Derivatives and Synthesis of 3-(2-Aminoethyl)-2-carboxy-5-hydroxycyclohepta [b] pyrrol-6 (1H)-one.
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چکیده
منابع مشابه
5-Imino-3,4-diphenyl-1H-pyrrol-2-one
The title compound, C16H12N2O, exists in the crystalline state as the 5-imino-3,4-di-phenyl--1H-pyrrol-2-one tautomer. The dihedral angles between the pyrrole and phenyl rings are 35.3 (2) and 55.3 (2)°. In the crystal, inversion dimers linked by pairs of N-H⋯N hydrogen bonds generate a graph-set motif of R 2 (2)(8) via N-H⋯N hydrogen bonds.
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The title compound, C(13)H(9)FN(2)O, a potential neuroprotective agent, consists of an indolinone and a pyrrolyl unit [dihedral angle between the ring planes = 4.9 (1)°]. An intra-molecular hydrogen bond between the carbonyl O atom and the NH group of pyrrole correlates with the Z arrangement of the substituents at the C=C bond. In the crystal, inversion dimers occur, linked by pairs of N-H⋯O b...
متن کامل3-Benzamido-1-benzoyl-1H-pyrrol-2(5H)-one
In the title compound, C(18)H(14)N(2)O(3), one of the phenyl rings is almost coplanar with the pyrrole ring [dihedral angle = 2.56 (14)°], whereas the other one is tilted by 63.01 (6)° with respect to the pyrrole ring. Since the NH group is shielded from possible acceptors, this group is not involved in hydrogen bonding.
متن کامل1-Benzyl-5-ethyl-5-hydroxy-1H-pyrrol-2(5H)-one
The title compound, C13H15NO2, was obtained as a by-product in the Grignard reaction of malimide. The dihedral angle between the five-memebred ring (r.m.s. deviation = 0.005 Å) and the benzene ring is 67.20 (14)°. The benzene ring and the ethyl chain lie to the same side of the five-membered ring. In the crystal, mol-ecules are linked by O-H⋯O hydrogen bonds, generating C(6) chains propagating ...
متن کامل1,3,6-Trimethylpyrano[4,3-b]pyrrol-4(1H)-one
All the non-H atoms of the title compound, C(10)H(11)NO(2), are almost coplanar [maximum deviation = 0.040 (3) Å]. The crystal structure is stabilized by C-H⋯O hydrogen bonds.
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ژورنال
عنوان ژورنال: Chemical and Pharmaceutical Bulletin
سال: 1963
ISSN: 0009-2363,1347-5223
DOI: 10.1248/cpb.11.1440